Gin Ichimaru (before Betrayal.)

Gin is a very mysterious man, since his almost constant smile and closed eyes, combined with his heavy use of sarcasm and mocking politeness, make it very difficult to discern his thoughts. In combat, he doesn't seem the least bit taken aback by the abilities of his opponent, even when they seemingly have an advantage. Many find his demeanor and appearance rather unsettling and there are very few who were willing to trust him. Gin is fully aware of the effect he has on others and more than once has toyed with people's emotional states for his own amusement. Ever since he was a child, dried persimmons had been his favorite food. Planting and raising many persimmon trees around the Third Division offices, Gin would make the dried persimmons himself before distributing them to other divisions. Due to mistaking a dried sweet potato for a dried persimmon, he developed a dislike for the former. During his free time, while still a captain, Gin would often go out for walks around Seireitei. Despite his hobby supposedly being people-watching, it would seem as though he also enjoyed hunting around and searching for an opportunity to create mischief with some poor victim.

Gin is a thin, tall, and youthful man with very sharp features, giving him a skeletal appearance, and bears to ears length unusual white hair. He keeps his eyes constantly narrowed to slits, rarely ever opening his eyes enough to reveal their bright sky blue-color.[2] He also keeps his face set in a wide mocking smile, which he only wipes off on rare occasions of annoyance, surprise, confusion, or even sadness. He wears a long, white robe over his normal Shinigami hakama. The hilt of his Zanpakutō is visible sticking out from under the robe through the opening down to his waist.